Thus the pi molecular orbital is higher in energy and is the highest occupied molecular orbital (the HOMO). The pi bond between the two carbon atoms has one node in the plane of the molecule. The sigma bond between the two carbon atoms does not have a node in the plane of the molecule. The wave with a single node has higher energy. If your workstation is enabled for JCE Software, you will see two videos below which compare the behavior of a standing wave with zero nodes versus a standing wave with one node (otherwise, see the drum animation below). ![]() The pi bond can be thought of as a standing wave with a single node in the plane of the molecule. Each of the two electrons in the pi bond (π bond) exists both above and below the plane of the four H atoms and the two C atoms. The pi bond (π bond) has two halves-one above the plane of the molecule, and the other below it. This is called a pi bond, Greek letter π. A second carbon-carbon bond is formed by the overlap of these two remaining p orbitals. The sp2 hybrid orbitals on each carbon atom involve the 2 s and two of the 2 p orbitals, leaving a single 2 p orbital on each carbon atom. By selecting N8 HOMO, you can see the pi orbital represented by the two lobes. This is actually sigma bonding between C-C and some sigma-like bonding around the Hs as well. To view the sigma bonding orbital, select N6. These overlap sideways to form a π bond, also shown in gray. Two p orbitals, one on each C atom, are shown in gray. ![]() Two of these overlap directly between the carbon atoms to form the σ bond. Three sp 2 hybrids around each carbon atom are indicated in color.
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![]() The by-the-glass program changes daily and always has a theme, so you’ll find something new each time you go. “It’s a chance for us to bring out the heavy hitters,” co-founder Zach Morris says. Stop by for weekly “Chalkboard Wines” specials - they open new bottles each Friday and pour them through the weekend till they’re gone. ![]() Since opening in 2019, Bloomsday has been a go-to for Euro-style all-day cafe vibes, a knowledgeable staff, and a wine list full of surprises. Go knowing you’ll be in good hands - and get hooked by the Fancy Wine Club. “The whole idea is to get people to dip their toe in the water,” says Wong, “and as they go, they can feel more comfortable and try new things.” Think of Fishtown Social as a delicately balanced wine: It’s light and fun, with a bit of funk to pique your wine curiosities but enough structure to make you feel grounded in familiarity. According to owner Vanessa Wong, building the list is a balancing act of selecting wines that feel exclusive while remaining approachable. It’s also exciting because no matter how much of a wine lover you are, there are likely several on this list you’ve never tried and several more you’ve never heard of (like Quinta do Infantado white port). It’s overwhelming because there are so many options for organic, biodynamic and natural wines made by small producers from underappreciated wine regions around the world. The wide selection of wines at Fishtown Social is simultaneously overwhelming and exciting. ![]() Go to try something new and explore unexpected vintages from unexpected places. Even if you sit at the bar solo, it won’t be long before you’re in conversation about some complex macabeo and dreamy shoegaze. To add to the experience, chef Eli Collins makes one-night-only snacks, with an on-theme “A-Side” and “B-Side” menu. “That level of concentration is something you can also apply to wine.” A.Bar next door rightfully gets attention for its craft cocktails and selection of low-intervention wines, but don’t sleep on A.Kitchen’s monthly Vine-yl Nights, at which Kinyon invites a resident expert for a wine-list takeover and full sides of vinyl to pair. “When I put a record on, as opposed to music on my phone, I tend to listen a little bit more seriously,” A.Kitchen beverage and service director Frank Kinyon tells us. Go to vibe with the Vine-yl Night playlists. ![]() Shows the player's location, and is accessed directly from the menu. The following behave as Key Items in certain ways, but they do not take up space in the pack as a physical item, and cannot be used in that way. Eequires passing through the Rijon Tunnel from Eagulou City, and requires Strength)Īllows the player to revive a Kabuto in Hayward City.Īllows the player to revive an Omanyte in Hayward City.Īllows the player to revive a Cranidos in Hayward City. The superstitious guy's house in the north-west of Hayward City. Warehouse and the Final Dungeon.Ĭan be exchanged for HM04 Strength at the Superstitious Guy's House in Hayward City.Īllows the player to enter the Eagulou City gym. Given by a man at Nations Burgers in Moraga Town. I'm not going to work on anymore Pokemon-related projects in the future, but I want to continue making games as long as I possibly can.Given in Gravel Town's Poké Mart upon entering it for the first time.Īllows the player to collect the Coins in Game Corner. Some have stuck with it for almost a decade, which I'm incredibly thankful for. I want to thank everyone who still wants to play the final version. I know some people have gotten fed up with waiting and jump ship, but I hope to bring them back when Prism is downloadable after TPP's run. Lots of people have been eagerly wanting to play the finished product and I don't want to let anyone down. For once, I wanted one of my ambitious ideas to make it all the way to the end. Sometimes my interest dies down, or sometimes I'm not happy with what I did so I decide to take a "break". I have a lot of game ideas, but throughout the last decade I've recognized a huge flaw that I have: With my projects, I never finish what I started. I'm incredibly thankful that this crew is helping me finish this hack. This is a collaborative effort now and without this help, I would not be able to complete this game because of my lack of free time. ![]() While I'm still working very hard on this hack, make no mistake. We'll be doing something that's never been done before: A crowd-sourced blind full play-through of a brand new game that won't be available to the public until the run is over. The crew that made Twitch Plays Pokemon Crystal were incredibly talented and they agreed to help me finish the hack if it could premiere on the official Twitch Plays Pokemon channel.Ĭorrect me if I'm wrong, but I believe this will be a first. Since almost half of my weekdays are spent either working or commuting, I had to get help to finish it. One year I didn't do anything at all and many of my breaks were months apart, because I wanted to focus my free time on other game projects that will never see the light of day. Between then and now, I've worked on it on and off. I started this hack back in 2007 when I went to junior college and I got my Computer Science degree three years ago and I'm working full-time while trying to save up enough money to buy a house and proceed with other new chapters in my life. I switched over to a crystal base with the Crystal Repository, a team is helping me complete this hack since I don't have much free time anymore, and it will premiere on Twitch Plays Pokemon in September and will be downloadable after the run is complete. I know it's been a long time since I've posted here, but I thought I'd give some insight to what's going on.Ī lot has happened (and will happen) this year. ![]() Notwithstanding, a sure sign of management confidence – or hubris – is KLA's use of cash, the largest expenditure of which were for the company's stock buybacks and payments of dividends to shareholders, at 78% of free cash flow. So, when one or all of these customers face troubles, it can spell trouble for KLA too. Semiconductor supply companies face a big concentration as there are a limited number of customers big enough to service the foundries and related companies. This is not an entirely logical constellation, however. Shares are up 46% in the past 12 months (more if you include the 1.1% dividend), versus the iShares Semiconductor ETF ( SOXX), which is up 39%. These solid fundamentals have helped KLAC shares outperform their fellow semiconductor stocks in recent months. KLA's free cash flow (cash from operations less capital expenditures) arrived at $815.7 million on a quarterly basis. The company sports a decent balance sheet with good liquidity, and operating cash flow exceeded $3.54 billion on a 12-month basis in its fiscal first quarter. Revenue of $2.4 billion and GAAP earnings of $5.41 per share came in at the upper end of KLA's guidance range. And it's one that remains intact following the company's fiscal first-quarter earnings report. ![]() The investment thesis for KLA ( KLA, $544.54) which offers semiconductor manufacturing solutions, is simple: fundamentals and industry outlook. Clearly, MRVL is looking to the future, though what the future looks like, beyond continued, if albeit lumpy expansion, remains difficult to discern. A look at Marvell's statement of cash flows shows that stock-based compensation, depreciation and amortization of intangible assets totaled $500 million for the most recently reported quarter, a figure which dwarfs a reported net loss of $207 million.Īlso notable also is the company's commitment to research and development, spending nearly $475 million in the last quarter. When looking at Marvell, or for that matter, most tech stocks, the earnings per share is not always the best measurement for success. This was particularly true in automotive/industrial, where the revenue rose 32% year-over-year. MRVL is not impervious to the headwinds facing the semi industry such as weakening demand in the consumer sector, but it was able to maintain growth in other end markets. For the six months ended July 29, MRVL reported revenue of $2.66 billion. The company had revenue of $1.34 billion, down 12% year-over-year but above the $1.32 billion reported in its fiscal first quarter. Marvell reported better-than-expected results in the second quarter of fiscal 2024. ![]() Off the price charts, the company – which makes semiconductors for data storage, communications and consumer markets – is holding its own too. Dividend yields are calculated by annualizing the most recent payout and dividing by the share price.Įverything seems to still be moving in the right direction at Marvell Technology ( MRVL, $55.58), including the share price which is up about 50% in the past 10 months or so. ![]() With that in mind, here are five of the best semiconductor stocks to buy now.ĭata is as of November 17. I also included chipmakers that offer some grist for stock pickers who like to look below the surface for opportunities. I used my decades of experience in quantitative analysis to identify the best stocks to buy among semiconductors, seeking companies that are simply fundamentally superior, with leadership positions in growing end markets. But for intrepid investors, it also created one of the greatest buying opportunities ever, particularly as many stocks have rebounded sharply in recent months. How we chose the best semiconductor stocksĢ022 was certainly one of the most difficult years for semiconductor stocks in recent memory. According to one estimate from the I nternational Data Corporation (IDC), the AI market is projected to surge from $118 billion in 2022 to $300 billion by 2026. Growth in AI is expected to continue too. Add to that artificial intelligence (AI), which has been a major positive catalyst for a number of stocks this year. ![]() On several projects, however, the actor has reportedly given some or all of her salary. Producing: Only Murders & 13 Reasons WhyĪnd Gomez's acting isn't her only source of income in the film and TV industry - she also owns her own production company, July Moon Productions, and has been an executive producer on 11 projects, including Only Murders in the Building and Netflix's 13 Reasons Why. It's highly possible that Gomez will continue earning a pretty large sum from the show in years to come. The popular show’s second season proved to be just as popular as its first, and a third season has already been confirmed. While Gomez's salary has not been reported, as the third lead of the show, chances are, she's raking in a similar figure. Variety reported that Gomez's co-stars Martin Short and Steve Martin were both making $600,000 per episode. In 2021, Gomez took on what is arguably another career-defining role in Hulu's Only Murders in the Building, a stylish, witty whodunit. Streaming Star: Only Murders In The Building However, after Allen was accused of sexual abuse, Gomez reportedly donated an amount to Time’s Up Legal Defense Fund that “far exceeded her salary for the film.” 3. In 2019, she landed a role in a high-profile Woody Allen project, A Rainy Day in New York. She also made a cameo appearance in The Big Short. Gomez went on to lend her voice to Hotel Transylvania, before appearing in films like Aftershock, Getaway, Rudderless, Behaving Badly, and The Fundamentals. "In the indie film world, I would rather get paid nothing to work with someone like Harmony Korine and have an amazing experience and the outcome be an incredible film I’m really proud of." (per ET Online). "One that I didn’t get paid for-really, at all-as Spring Breakers, which turned out to be one of my favorite projects I’ve ever done," she told InStyle. It’s unclear exactly how much Gomez made for her role in the film, according to Gomez’s co-star, Pretty Little Liars’ Ashely Benson, none of the actors made much as it was an indie project with a low budget of just $5 million. “You've got to push yourself as an actor if you're going to grow, and that's what we're doing, pushing ahead, learning all the time.” “I feel like it's evolution,” she told The Guardian in 2013. The role gave her a chance to break away from her Disney girl-next-door image. In 2012, she starred as Faith in the dark coming-of-age movie Spring Breakers. Shortly after Wizards of Waverley Place, she really began to make her mark in Hollywood with a string of film roles. Breaking Into Hollywood: Spring Breakers, The Big Short, & A Rainy Day in New YorkĪfter becoming a household name for Millennials all over the world thanks to Disney Channel, Gomez has continued to showcase her range as an actor with roles in over 100 projects. According to Money Inc., she was paid $3,000 per episode and ultimately appeared in 13 episodes altogether.Ģ. ![]() Gomez began her career at the young age of 7 when she landed a role on the famous kids' show Barney & Friends. 8 Ways Selena Gomez Makes Her Millions 1. With her new documentary and season three of Only Murders in the Building on the way, we did a little digging - just how much money does Gomez actually make? Here is a breakdown of the pop star and actor's staggering net worth. She is also giving her fans an inside glimpse at her journey with her own mental health. That’s why in 2022, Gomez launched a wellness app called Wondermind. Not only is she raking in millions from her work on and off screen - but she is also a prolific businesswoman whose brand collaborations, investments, and social media presence also add a significant sum to her salary.īut sometimes, career success doesn’t equal mental wellness. Gomez is an actor, producer, and businesswoman with an ever-growing net worth. In her new A pple TV+ documentary, My Mind & Me, her “six-year journey into a new light” is expected to be explored. Despite career successes that range from hit pop albums, sell-out stadium tours, a critically acclaimed turn in Hulu's sharp whodunit Only Murders in the Building, producer credits on shows like 13 Reasons Why, Only Murders in the Building, and Selena+Chef and a beauty line called Rare Beauty, Gomez has had her struggles too. For Selena Gomez, who first shot to fame as a Disney starlet in Wizards of Waverley Place (and even younger in Barney & Friends), her life in the spotlight has certainly come with ups and downs. Being thrust into the public eye at a young age is rarely easy. One of the most significant advantages of transparent materials is their ability to allow light to pass through them easily, without significant distortion or scattering. Transparent materials, such as glass and clear plastic, provide a clear view of what’s inside or beyond, making them ideal for windows, eyeglasses, and containers. The property of transparency offers numerous advantages and benefits in various applications. Translucent Pros and Cons Transparent Pros & Cons Transparent Pros ![]() Both transparent and translucent materials have practical applications in various fields, from architecture and design to photography and optics.Both transparent and translucent materials have the ability to transmit light, but they differ in the clarity of the view they provide.Both transparent and translucent materials have practical applications in various fields, from architecture and design to photography and optics. Examples of translucent materials include frosted glass, wax paper, and some types of plastic. Translucent materials, on the other hand, allow some light to pass through, but scatter or diffuse it in a way that obscures a clear view of objects on the other side. Transparent materials, such as glass and clear plastic, allow light to pass through without significant distortion or scattering, resulting in a clear view of objects on the other side. Translucent Similaritiesīoth transparent and translucent materials have the ability to transmit light, but they differ in the clarity of the view they provide. On the other sideTranslucent objects do not have this property of reflection, so they can appear hazy even when they are not directly facing the light. ![]() Transparent objects have the property of reflection, which means that they appear clear even when they are not directly facing the light. In contrast, translucent materials like frosted glass or wax paper scatter light in a way that obscures a clear view of objects on the other side. Transparent materials such as glass and clear plastic allow for a clear view of the objects on the other side, without significant distortion or scattering. While both allow light to pass through them, they differ in the amount of scattering and distortion that occurs. Transparent and translucent materials are two of the most commonly used terms when it comes to describing the properties of various materials. Key Differences Between Transparent And Translucent These materials are frequently used in architectural elements, lampshades, and decorative objects, where the diffusion of light adds to the visual appeal. Common examples of translucent materials include frosted glass, wax paper, and certain types of plastics. This property of translucent materials creates a sense of softness or diffuseness in the transmitted light, which can be used to create a pleasant ambient lighting effect or ensure privacy. Translucent is a term used to describe a material that allows some amount of light to pass through it, but diffuses or scatters the light in a way that obstructs a clear view of objects on the other side. Its ability to create a clear view creates a significant impact in many industries. The transparency property is highly valuable and widely used in fields such as optics, photography, architecture, and design. ![]() Examples of transparent materials include glass, clear plastic, and clean air. Transparent materials are commonly used in various applications such as windows, eyeglasses, and containers as they provide a clear view of what lies inside or beyond. This quality enables objects on the other side of a transparent object to be clearly seen. “Transparent” is a term used to describe a material or substance that allows light to pass through it easily, without significant distortion or scattering. Conclusion: What Is The Difference Between Transparent And Translucent? What Is Transparent?.Comparison Table: 9 Key Differences Between Transparent And Translucent.Key Differences Between Transparent And Translucent. Needless to say that having plenty of power simply gives you more versatility with your blend. More power means you can blend frozen fruits, ice, or even hard veggies. So make sure you check its power before buying.Ī good rule of thumb is that any personal blender that has 200-500 watts of blending power is acceptable. Although be aware that some of them can be so low that they can’t practically blend smoothies with a smooth consistency. A secure, drip-free lid is necessary to prevent spillage while you’re on the go.īase power: You may not find overwhelming power with single-serve blenders as compared to a typical countertop blender, which can be expected. Aside from the container/s that come with it, check if it also has spill-proof travel lid/s to make it easy to carry and handle. ![]() Considering that it’s a personal blender, you need to be on the lookout for the package inclusions of the particular blender you’re buying. Type of travel bottle : Having an accompanying travel container is important. However, keep in mind that rechargeable blenders may not work well for tougher ingredients as compared to a typical personal blender that you plug into a wall socket. If you’re looking for a fresh blend to consume immediately right after, then a rechargeable blender is definitely for you. Talk about portability and convenience, right? This type of blender runs on lithium-ion batteries similar to smartphones, has an accompanying USB cable with them for charging, and can be charged using your ordinary gadget’s power bank. ![]() Type of personal blender : Rechargeable blenders are now becoming a trend due to their portability. Here are some things to consider to help you narrow down your selection: ![]() *E-PASS Portable is no longer available for purchase. All E-PASS Xtra transponders will continue to work throughout 19 states and be fully supported as part of the E-PASS family of products. *E-PASS Xtra is no longer available for purchase.
![]() ![]() Our hosted software are virus and malware scanned with several antivirus programs using ( NOTE! Just one virustotal warning is 99.9% a false positive. Version history available = Complete changelog on our site. Old versions available = Download old versions of the program. Portable version available = Download the portable version and you can just extract the files and run the program without installation. It may not contain the latest versions.ĭownload old versions = Free downloads of previous versions of the program.ĭownload 64-bit version = If you have a 64bit operating system you can download this version.ĭownload portable version = Portable/Standalone version meaning that no installation is required, just extract the files to a folder and run directly. Visit developers site = A link to the software developer site.ĭownload (mirror link) = A mirror link to the software download. Be careful when you install the software and disable addons that you don't want! Ad-Supported = The software is bundled with advertising. No installation is required.ĭownload beta = It could be a Beta, RC(Release Candidate) or an Alpha / Nightly / Unstable version of the software.ĭownload 15MB = A direct link to the software download. Portable version = A portable/standalone version is available. Free Trial version available for download and testing with usually a time limit or limited functions. ![]() Trialware = Also called shareware or demo. It may be disabled when installing or after installation. Free software Ads = Free Download software and open source code but supported by advertising, usually with a included browser toolbar. Freeware Ads = Download Free software but supported by advertising, usually with a included browser toolbar. Free software Trialware = Download Free software and also open source code but some parts are trial/shareware. Free software = Download Free software and also open source code also known as FOSS (Free and Open Source Software). Freeware Trialware = Download Free software but some parts are trial/shareware. RECENTLY UPDATED = The software has been updated the last 31 days. NO LONGER DEVELOPED = The software hasn't been updated in over 5 years. Type and download NO MORE UPDATES? = The software hasn't been updated in over 2 years. Version number / Beta version number / Update version number and when it whas released. Explanation: NEW SOFTWARE= New tool since your last visit NEW VERSION= New version since your last visit NEW REVIEW= New review since your last visit NEW VERSION= New version Latest version Both kinds of HD live streaming encoders take RAW video files and convert them into digital files, allowing you to stream video content online. ![]() While hardware and software encoders are slightly different they function similarly.
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